Space Oddity by David Bowie
When I saw The Secret Life Of Walter Mitty (2013) it was surprising to see this song in the movie. I was also surprised to have one of my students request this song just recently. 
Maybe I shouldn't have been surprised. It's a pretty good song. The chord changes surprise me every time I play them. 
Hal Stead
https://youtu.be/m5UzpQVv2rc